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If you can run some code that looks like this you should be able to find it
var collection = Membership.GetAllUsers();
string[] roles = System.Web.Security.Roles.GetAllRoles();
foreach (MembershipUser user in collection)
{
foreach (string role in roles)
{
if (role.Equals(user.UserName))
return "same username and role name " + role;
}
}
}
string[] roles = System.Web.Security.Roles.GetAllRoles();
should return all roles defined. Therefor I quess the problem is in your RoleProvider secion of web.config.
The error isn't very specific about which user or group is causing the problem.